Oxide Materials at the Two-Dimensional Limit by Falko P. Netzer, Alessandro Fortunelli

By Falko P. Netzer, Alessandro Fortunelli

This e-book summarizes the present wisdom of two-dimensional oxide fabrics. the elemental houses of 2-D oxide platforms are explored by way of atomic constitution, digital habit and floor chemistry. the idea that of polarity in opting for the soundness of 2-D oxide layers is tested, cost move results in ultrathin oxide movies are reviewed in addition to the function of defects in 2-D oxide motion pictures. the unconventional constitution options that follow in oxide platforms of low dimensionality are addressed, and a bankruptcy giving an summary of cutting-edge theoretical equipment for digital constitution choice of nanostructured oxides is incorporated. specific emphasis is given to a balanced view from the experimental and the theoretical facet. Two-dimensional fabrics, and 2-D oxides particularly, have amazing habit as a result of dimensionality and proximity results. a number of chapters deal with prototypical version platforms as illustrative examples to debate the atypical actual and chemical homes of 2-D oxide platforms. The chapters are written via well known specialists within the field.

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Surnev S, Kresse G, Sock M et al (2001) Surface structures of ultrathin vanadium oxide films on Pd(111). Surface Sci 495:91–196 54. Surnev S, Sock M, Kresse G et al (2003) Unusual CO adsorption sites on vanadium oxide— Pd(111) “inverse model catalyst” surfaces. J Phys Chem B 107:4777–4785 55. Sedona F, Rizzi GA, Agnoli S et al (2005) UltrathinTiOx films on Pt(111): A LEED, XPS, and STM investigation. J Phys Chem B 109:24411–24426 56. Barcaro G, Agnoli S, Sedona F et al (2009) Structure of reduced ultrathin TiOx polar films on Pt(111).

Surface Sci 606:803–807 20. Obermüller T, Steurer W, Surnev S et al (2013) Kinetic asymmetry in the growth of two-dimensional Mn oxide nanostripes. Phys Rev B 88:235410 21. Obermüller T (2015) Growth of transition metal oxides in 2D layers: probing and tuning the properties of matter at the atomic scale. PhD thesis, University of Graz 22. Müller F, de Masi R, Reinicke DK et al (2002) Epitaxial growth of MnO/Ag(001) films. Surface Sci 520:158–172 23. Schoiswohl J, Agnoli S, Xu B et al (2005) Growth and thermal behaviour of NiO nanolayers on Pd(100).

44] have presented an STM view of an intermediate stage of the oxidation, performed with atomic oxygen, of the FeO(111) bilayer on Pd (111). We recall that the FeO(111) bilayer on Pd(111) is isostructural with the one on Pt(111). 17a, b displays STM images, in which O–Fe–O islands (bright contrast) coexist with O-adatom line dislocations, the latter are formed during the initial stages of the oxidation. Panel (c) gives a schematic picture of the structural changes during the bilayer-trilayer transformation [44].

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